Taking off a mirror coatingThe best way to take off a mirror coating is by means of etching. Aluminium etches away quickly in a solution of Copper(II)Chloride. An alternative way to get Cu dissolved in the HClaq solution is by means of electrolysis. What you need for this method is a glass container, two beefy copper electrodes and a current source able to deliver at least 1 Ampere. It will operate at only a few Volts.
The reaction at the anode will slowly dissolve the copper electrode in the acid. The cathode will attract surplus copper from the solution, which can be seen as a deposit on the electrode. A part of the copper remains dissolved however, and gradually colours the fluid green (see right image). When the current decreases, wiggle the electrodes a bit (especially the anode) to get the current up again. At some point the current drops quickly after wiggling; this indicates that the solution is saturated with copper. The solution is ready for use!
First make a tape rim around the mirror edge, so that the fluid will stay on the mirror surface. I used paper painters tape for this. Then pour the CuCl2 solution on and move the mirror a little. Do not to spill a single drop, because it will etch any metal. I use a large plastic bin to keep the lot in. After only 15 seconds the coating becomes translucent, and after 1 or 2 minutes the process is completed. Pour the solution back in the container for future use and rinse thoroughly. You can neutralize what is left with e.g. sodiumcarbonate (NaHCO3) aka baking powder. |